Sonochemical Synthesis of Porous Nanowall Co3o4/Nitrogen-Doped Reduced Graphene Oxide As an Efficient Electrode Material for Supercapacitors Publisher



Naderi HR¹ ; Norouzi P^{1, 2} ; Ganjali MR^{1, 2} ; Gholipourranjbar H¹
Source: Journal of Materials Science: Materials in Electronics Published:2017

Abstract

A composite of nitrogen-doped reduced graphene oxide (NRGO) with nano-sized Co3O4 was prepared using a sonochemical method. The prepared Co3O4/NRGO samples were assessed through field emission scanning electron microscopy, X-ray diffraction, X-ray photoemission spectroscopy, and Raman spectroscopy to obtain chemical, structural and morphological information. The resulting composite (Co3O4/NRGO) was evaluated as a candidate for building supercapacitor electrodes. In this line the electrochemical performance of the tested materials were studied through cyclic voltammetry, galvanostatic charge/discharge, electrochemical impedance spectroscopy, and continues cyclic voltammetry. The electrochemical tests were performed using 3 M KCl solutions as the electrolyte. The evaluations on Co3O4/NRGO-based electrodes revealed the material to have a specific capacitance (SC) of 763 F g−1 at a scan rate of 2 mV s−1, an energy density (ED) of 138 W h kg−1, and a high rate capability. Continues cyclic voltammetry evaluations using Co3O4/NRGO-based electrodes proved the electrodes to be capable of maintaining almost 98.9% of its initial SC after 4000 cycles. Based on the electrochemical evaluations the synthesized nanocomposite was proven to possess the merits of both of its ingredients. © 2017, Springer Science+Business Media, LLC.