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Adsorptive Removal of Fluoride From Aqueous Solution Using Single- and Multi-Walled Carbon Nanotubes Publisher



Dehghani MH1, 2 ; Haghighat GA1 ; Yetilmezsoy K3 ; Mckay G4 ; Heibati B1 ; Tyagi I5 ; Agarwal S5, 6 ; Gupta VK5, 6
Authors
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Authors Affiliations
  1. 1. Department of Environmental Health Engineering, School of Public Health, Tehran University of Medical Sciences, Tehran, Iran
  2. 2. Institute for Environmental Research, Center for Solid Waste Research, Tehran, Iran
  3. 3. Department of Environmental Engineering, Faculty of Civil Engineering, Yildiz Technical University, Davutpasa Campus, Esenler, Istanbul, 34220, Turkey
  4. 4. Division of Sustainability, Hamad Bin Khalifa University, Education City, Qatar Foundation, Doha, Qatar
  5. 5. Department of Chemistry, Indian Institute of Technology, Roorkee, 247667, India
  6. 6. Department of Applied Chemistry, University of Johannesburg, Johannesburg, South Africa

Source: Journal of Molecular Liquids Published:2016


Abstract

In the present study, defluoridation study of liquid phase with the help of multi-walled carbon nanotubes (MWCNTs) and single-walled carbon nanotubes (SWCNTs) were well investigated and elucidated. The impact of different experimental conditions such as solution pH, initial fluoride concentration, adsorbent dose, and contact time was well studied and optimized for the maximum fluoride removal from water. The experimental data were fitted by the Freundlich, Langmuir and Dubinin-Radushkevich (D-R) isotherm models and the related equilibrium constants were calculated. The results of the isotherm studies showed that fluoride removal by both adsorbents followed the Freundlich isotherm model. Kinetic studies were conducted and the results demonstrated that the experimental data were fitted well with the pseudo-second order kinetic model. Furthermore, two multiple regression-based equations were also derived to model the removal of fluoride from aqueous solutions by the carbon nanotubes. This study demonstrated that the polynomial equations satisfactorily described the behavior of the present defluoridation process for both MWCNTs (R2 = 0.913) and SWCNTs (R2 = 0.941). © 2016 Elsevier B.V. All rights reserved.