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Adsorption of P-Cresol on Al2o3 Coated Multi-Walled Carbon Nanotubes: Response Surface Methodology and Isotherm Study Publisher



Jaafari J1, 2 ; Ghozikali MG3 ; Azari A4 ; Delkhosh MB5 ; Javid AB6 ; Mohammadi AA7 ; Agarwal S8 ; Gupta VK8 ; Sillanpaa M9, 10 ; Tkachev AG11 ; Burakov AE11
Authors
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Authors Affiliations
  1. 1. School of Health, Guilan University of Medical Sciences, Rasht, Iran
  2. 2. Department of Environmental Health, School of Public Health, Tehran University of Medical Sciences, Tehran, Iran
  3. 3. Department of Environmental Health, School of Public Health, Tabriz University of Medical Sciences, Tabriz, Iran
  4. 4. Research Center for Environmental Determinants of Health, Kermanshah University of Medical Sciences, Kermanshah, Iran
  5. 5. Department of Occupational Health Engineering, Neyshabur University of Medical Sciences, Neyshabur, Iran
  6. 6. School of Public Health, Shahroud University of Medical Sciences, Shahroud, Iran
  7. 7. Department of Environmental Health Engineering, Neyshabur University of Medical Sciences, Neyshabur, Iran
  8. 8. Department of Applied Chemistry, University of Johannesburg, Johannesburg, South Africa
  9. 9. Laboratory of Green Chemistry, School of Engineering Science, Lappeenranta University of Technology, Sammonkatu 12, Mikkeli, FI-50130, Finland
  10. 10. Department of Civil and Environmental Engineering, Florida International University, 10555, West Flagler Street, Miami, 33174, FL, United States
  11. 11. Tambov State Technical University, 106, Sovetskaya Str., Tambov, 392000, Russian Federation

Source: Journal of Industrial and Engineering Chemistry Published:2018


Abstract

The development and design of adsorbents with high adsorption performance is an effective method of removing p-Cresol from effluent for environmental protection. Therefore, an Al2O3 coated multiwalled carbon nanotubes (MWNTs) composite for adsorption of p-Cresol from aqueous solution was synthesized. The p-Cresol concentration was determined by estimating the absorbance of the sample solution on a DR5000 UV/vis spectrophotometer. Box–Behanken design (BBD) was involved in the optimization of p-Cresol adsorption upon Al2O3 coated MWNTs adsorbent against the process parameters time, pH and adsorbent dose. The effects of these factors were studied in the ranges 5–40 min, 4–10, and 0.2–2 g L−1, respectively. The lack of fit obtained for this model was 0.357 which confirmed that the model is highly significant and the experiments are accurate and reliable. The results showed that adsorption isotherms fit well with the pseudo-second-order kinetic model and Langmuir isotherm model and Qmax was calculated to be 54.05 mg/g. Our results demonstrate that Al2O3 coated MWNTs has the potential to be used as an effective adsorbent for the rapid uptake of p-Cresol from aqueous solutions. © 2017 The Korean Society of Industrial and Engineering Chemistry