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Removal of Linear Alkyl Benzene Sulfonate From Aqueous Solutions by Functionalized Multi-Walled Carbon Nanotubes Publisher



Heibati B1, 2 ; Ghoochani M2 ; Albadarin AB3 ; Mesdaghinia A4 ; Makhlouf ASH5 ; Asif M6 ; Maity A7, 9 ; Tyagi I8 ; Agarwal S8, 9 ; Gupta VK8, 9
Authors
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Authors Affiliations
  1. 1. Department of Occupational Health Engineering, Faculty of Health, Health Sciences Research Center, Mazandaran University of Medical Sciences, Sari, Iran
  2. 2. Department of Environmental Health Engineering, Faculty of Public Health, Tehran University of Medical Sciences, Tehran, Iran
  3. 3. Department of Chemical and Environmental Sciences, University of Limerick, Ireland
  4. 4. Center for Water Quality Research (CWQR), Institute for Environmental Research (IER), Tehran University of Medical Sciences, Tehran, Iran
  5. 5. Department of Manufacturing Engineering, College of Engineering and Computer Science, University of Texas Pan-American, United States
  6. 6. Department of Chemical Engineering, King Saud University Riyadh, Saudi Arabia
  7. 7. National Centre for Nanostructured Materials, CSIR Material Science and Manufacturing, Pretoria, 0001, South Africa
  8. 8. Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee, 247667, India
  9. 9. Department of Applied Chemistry, University of Johannesburg, Johannesburg, South Africa

Source: Journal of Molecular Liquids Published:2016


Abstract

This paper explores the possibility of employing Oxidized Multiwalled Carbon Nanotubes (MWCNT-COOH) for the removal of toxic Linear Alkyl benzene Sulfonate (LAS). LAS is among the most toxic industrial and house hold waste surfactants. This study discusses the feasibility of removing LAS from aqueous solutions using MWCNT-COOH. The effects of operational parameters such as solution pH, LAS concentration and contact time on the removal of LAS were studied. The four linear forms of Langmuir, Freundlich, Dubinin Radushkevich (D-R) and Temkin models were applied to determine the best fit of equilibrium expressions. Our results showed that the experimental adsorption isotherm complies with Freundlich model. The maximum adsorption capacity was determined to be 62.5 mg/g with an initial LAS concentration of 4 mg/L at pH 3 in 45 min. Fitting of the experimental results to kinetic models showed the relevance of the pseudo second-order (R2 > 0.99) model for LAS. Our results confirmed that MWCNT-COOH would be promising adsorbents for LAS removal in aqueous solution. © 2015 Elsevier B.V.