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Enhanced Removal of Acidic Dyes (Ab1 and Mo) From Binary Systems Using Anion Exchange Membrane Bii: Kinetic, Isotherm, and Thermodynamic Analyses Publisher Pubmed



Naz A1 ; Jaleel F2 ; Zafar S1 ; Younas M3, 4 ; Taheri E5 ; Fatehizadeh A5 ; Rezakazemi M6
Authors
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Authors Affiliations
  1. 1. Department of Chemistry, The Government Sadiq College Women University, Bahawalpur, 63100, Pakistan
  2. 2. Institute of Chemistry, The Islamia University of Bahawalpur, Rahim Yar Khan Campus Pakistan, Rahim Yar Khan, 64200, Pakistan
  3. 3. Department of Chemical Engineering, Faculty of Mechanical, Chemical and Industrial Engineering, University of Engineering and Technology, Peshawar, 25120, Pakistan
  4. 4. CAS Key Laboratory of Urban Pollutant Conversion, Institute of Urban Environment, Chinese Academy of Sciences, 1799 Jimei Road, Xiamen, 361021, China
  5. 5. Department of Environmental Health Engineering, School of Health, Isfahan University of Medical Sciences, Isfahan, Iran
  6. 6. Faculty of Chemical and Materials Engineering, Shahrood University of Technology, Shahrood, Iran

Source: Environmental Science and Pollution Research Published:2024


Abstract

In the current work, the adsorption of acid black 1 (AB1), a hair dye, and methyl orange (MO) on anion exchange membrane BII (AEM-BII) in a binary system was studied experimentally. The effects study for contact time, adsorbent’s and adsorbates’ concentration, and temperature of aqueous media on the AB1 and MO removal, AEM-BII recovery, and reusability were also investigated. The highest removal was observed at optimum conditions, 150-min contact time and 5 g L−1 of adsorbent for AB1 (91.2%) and MO (83.4%). Adsorption kinetics was estimated by pseudo-first-order (PFO) and pseudo-second-order (PSO) kinetics. The experimental findings were fitted well by PSO kinetics with an adsorption capacity of 19.45 ± 0.93 and 19.34 ± 0.84 mg g−1 for ABI and MO, respectively. Moreover, the adsorption isotherm study confirmed that AB1 and MO adsorption by AEM-BII from the binary system was followed by Langmuir isotherms. Adsorption thermodynamics revealed that adsorption of both AB1 and MO by AEM-BII was endothermic and spontaneous. Moreover, the desorption phenomenon of ABI and MO from the loaded AEM-BII showed that dye removal from AEM-BII was found to be 74.95%, demonstrating AEM-BII can be considered as good adsorbent for acidic dyes from the binary system. © The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2024.
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