Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology

Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology Publisher

Bahrololoomi Fard SM¹ ; Ahmadi SH² ; Hajimahmodi M³ ; Fazaeli R¹ ; Amini M³

Show Affiliations

1. Department of Chemistry, Faculty of Science, South Tehran Branch, Islamic Azad University, Tehran, Iran
2. Department of Environmental Analytical Chemistry, Chemistry and Chemical Engineering Research Center of Iran, Tehran, 1946813151, Iran
3. Medicinal Chemistry, Drug and Food Control Department, Faculty of Pharmacy, Tehran University of Medical Sciences, Tehran, Iran

Source: Analytical Methods Published:2019

Abstract

In the present study, different ionic liquid modified magnetic nanoparticles have been prepared and tested as nano-metric adsorbents for the analysis of eight phthalic acid esters (PAEs) from water samples using dispersive micro solid-phase extraction (D-micro-SPE). Determination and identification of the PAEs were performed by ultra performance liquid chromatography-tandem mass spectrometry. Compared with ionic liquid functionalized magnetic nanoparticle adsorbents, benzimidazolium-chloride modified iron oxide nanoparticles (Fe3O4@[Bimi]Cl NPs) show higher extraction efficiency for all PAEs. The Fe3O4@[Bimi]Cl NPs were fully characterized by Fourier-transform infrared spectroscopy, field emission-scanning electron microscopy, energy-dispersive X-ray spectroscopy, transmission electron microscopy, X-ray diffraction, and zeta potential analysis. The D-micro-SPE conditions, including sample pH, adsorbent dosage, extraction time, type of desorption solvent, volume of elution solvent, and desorption time, were optimized using both univariate and multivariate techniques based on response surface methodology. Under optimized conditions, the developed method was validated for PAE analysis in different water samples, including river water, tap water, bottled mineral water, well water, and wastewater. The method features wide linearity and low limits of detection ranging from 0.002-0.012 μg L-1. In addition, recoveries ranging from 83% to 111% with a precision (RSDs) of lower than 8% were obtained. Therefore, the proposed method is an efficient pretreatment procedure and can be utilized for the sensitive determination of PAEs in different water samples. This journal is © The Royal Society of Chemistry.

Style	Citing Format
MLA	Bahrololoomi Fard SM, et al.. "Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology." Analytical Methods, vol. 12, no. 1, 2019, pp. 73-84.
APA	Bahrololoomi Fard SM, Ahmadi SH, Hajimahmodi M, Fazaeli R, Amini M (2019). Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology. Analytical Methods, 12(1), 73-84.
Chicago	Bahrololoomi Fard SM, Ahmadi SH, Hajimahmodi M, Fazaeli R, Amini M. "Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology." Analytical Methods 12, no. 1 (2019): 73-84.
Harvard	Bahrololoomi Fard SM et al. (2019) 'Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology', Analytical Methods, 12(1), pp. 73-84.
Vancouver	Bahrololoomi Fard SM, Ahmadi SH, Hajimahmodi M, Fazaeli R, Amini M. Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology. Analytical Methods. 2019;12(1):73-84.
BibTex	@article{ author = {Bahrololoomi Fard SM and Ahmadi SH and Hajimahmodi M and Fazaeli R and Amini M}, title = {Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology}, journal = {Analytical Methods}, volume = {12}, number = {1}, pages = {73-84}, year = {2019} }
RIS	TY - JOUR AU - Bahrololoomi Fard SM AU - Ahmadi SH AU - Hajimahmodi M AU - Fazaeli R AU - Amini M TI - Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology JO - Analytical Methods VL - 12 IS - 1 SP - 73 EP - 84 PY - 2019 ER -

Style

Citing Format

MLA

Bahrololoomi Fard SM, et al.. "Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology." Analytical Methods, vol. 12, no. 1, 2019, pp. 73-84.

APA

Bahrololoomi Fard SM, Ahmadi SH, Hajimahmodi M, Fazaeli R, Amini M (2019). Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology. Analytical Methods, 12(1), 73-84.

Chicago

Bahrololoomi Fard SM, Ahmadi SH, Hajimahmodi M, Fazaeli R, Amini M. "Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology." Analytical Methods 12, no. 1 (2019): 73-84.

Harvard

Bahrololoomi Fard SM et al. (2019) 'Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology', Analytical Methods, 12(1), pp. 73-84.

Vancouver

Bahrololoomi Fard SM, Ahmadi SH, Hajimahmodi M, Fazaeli R, Amini M. Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology. Analytical Methods. 2019;12(1):73-84.

BibTex

@article{ author = {Bahrololoomi Fard SM and Ahmadi SH and Hajimahmodi M and Fazaeli R and Amini M}, title = {Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology}, journal = {Analytical Methods}, volume = {12}, number = {1}, pages = {73-84}, year = {2019} }

RIS

TY - JOUR
AU - Bahrololoomi Fard SM
AU - Ahmadi SH
AU - Hajimahmodi M
AU - Fazaeli R
AU - Amini M
TI - Preparation of Magnetic Iron Oxide Nanoparticles Modified With Imidazolium-Based Ionic Liquids As a Sorbent for the Extraction of Eight Phthalate Acid Esters in Water Samples Followed by Uplc-Ms/Ms Analysis: An Experimental Design Methodology
JO - Analytical Methods
VL - 12
IS - 1
SP - 73
EP - 84
PY - 2019
ER -

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