Regio- and Diastereoselective Kmno4/Rco2h Mediated Acyloxyarylation of Chalcones

Regio- and Diastereoselective Kmno4/Rco2h Mediated Acyloxyarylation of Chalcones – an Indirect Α-Arylation of Chalcones Publisher

Adib M¹ ; Rajaidaryasarei S¹ ; Pashazadeh R¹ ; Mahdavi M² ; Madadi M¹ ; Jahani M¹

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1. School of Chemistry, College of Science, University of Tehran, PO Box 14155-6455, Tehran, Iran
2. Endocrinology and Metabolism Research Center, Endocrinology and Metabolism Clinical Sciences Institute, Tehran University of Medical Sciences, Tehran, Iran

Source: European Journal of Organic Chemistry Published:2020

Abstract

A MnVII-mediated regio- and diastereoselective acyloxyarylation of chalcones is unveiled. Heating a solution of a chalcone and an arylboronic acid in an aliphatic carboxylic acid at 80 °C for 1 h afforded the corresponding 1-acyloxy-3-oxo-1,2,3-triarylpropanes in high yields. The β-acyloxy-α-arylation/elimination sequence can be regarded as an indirect α-arylation of chalcones. © 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Style	Citing Format
MLA	Adib M, et al.. "Regio- and Diastereoselective Kmno4/Rco2h Mediated Acyloxyarylation of Chalcones – an Indirect Α-Arylation of Chalcones." European Journal of Organic Chemistry, vol. 2020, no. 14, 2020, pp. 2045-2051.
APA	Adib M, Rajaidaryasarei S, Pashazadeh R, Mahdavi M, Madadi M, Jahani M (2020). Regio- and Diastereoselective Kmno4/Rco2h Mediated Acyloxyarylation of Chalcones – an Indirect Α-Arylation of Chalcones. European Journal of Organic Chemistry, 2020(14), 2045-2051.
Chicago	Adib M, Rajaidaryasarei S, Pashazadeh R, Mahdavi M, Madadi M, Jahani M. "Regio- and Diastereoselective Kmno4/Rco2h Mediated Acyloxyarylation of Chalcones – an Indirect Α-Arylation of Chalcones." European Journal of Organic Chemistry 2020, no. 14 (2020): 2045-2051.
Harvard	Adib M et al. (2020) 'Regio- and Diastereoselective Kmno4/Rco2h Mediated Acyloxyarylation of Chalcones – an Indirect Α-Arylation of Chalcones', European Journal of Organic Chemistry, 2020(14), pp. 2045-2051.
Vancouver	Adib M, Rajaidaryasarei S, Pashazadeh R, Mahdavi M, Madadi M, Jahani M. Regio- and Diastereoselective Kmno4/Rco2h Mediated Acyloxyarylation of Chalcones – an Indirect Α-Arylation of Chalcones. European Journal of Organic Chemistry. 2020;2020(14):2045-2051.
BibTex	@article{ author = {Adib M and Rajaidaryasarei S and Pashazadeh R and Mahdavi M and Madadi M and Jahani M}, title = {Regio- and Diastereoselective Kmno4/Rco2h Mediated Acyloxyarylation of Chalcones – an Indirect Α-Arylation of Chalcones}, journal = {European Journal of Organic Chemistry}, volume = {2020}, number = {14}, pages = {2045-2051}, year = {2020} }
RIS	TY - JOUR AU - Adib M AU - Rajaidaryasarei S AU - Pashazadeh R AU - Mahdavi M AU - Madadi M AU - Jahani M TI - Regio- and Diastereoselective Kmno4/Rco2h Mediated Acyloxyarylation of Chalcones – an Indirect Α-Arylation of Chalcones JO - European Journal of Organic Chemistry VL - 2020 IS - 14 SP - 2045 EP - 2051 PY - 2020 ER -

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