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Continuous Degradation of an Organic Pollutant Using Heterogeneous Magnetic Biocatalyst and Cfd Analysis of the Process Publisher



Zolfaghari P1 ; Aghbolaghy M2 ; Karimi A3 ; Khataee A4, 5, 6
Authors
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Authors Affiliations
  1. 1. Department of Chemical Engineering, Faculty of Chemical and Petroleum Engineering, University of Tabriz, Tabriz, 51666-16471, Iran
  2. 2. Department of Chemical Engineering, University of Saskatchewan, 57 Campus Drive, Saskatoon, S7N 5A9, SK, Canada
  3. 3. Faculty of Advanced Technologies in Medicine, Iran University of Medical Sciences, Tehran, 14496-14535, Iran
  4. 4. Research Laboratory of Advanced Water and Wastewater Treatment Processes, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, 51666-16471, Iran
  5. 5. Health Promotion Research Center, Iran University of Medical Sciences, Tehran, 1449614535, Iran
  6. 6. Department of Materials Science and Nanotechnology Engineering, Faculty of Engineering, Near East University, 99138 Nicosia, Mersin 10, Turkey

Source: Process Safety and Environmental Protection Published:2019


Abstract

GOx/Fe3O4/TiO2 on natural kissiris support was produced by consecutive preparation of TiO2/kissiris and Fe3O4/TiO2/kissiris followed by immobilization of Glucose Oxidize (GOx). This magnetic biocatalyst was used for continuous elimination of Malachite Green (MG) from aqueous solution in a packed bed reactor through bio-Fenton reaction. The biocatalyst was characterized by FT-IR, EDX and SEM analyses. Residence time distribution (RTD) of MG in the reactor was measured and parameters of the Langmuir-Hinshelwood kinetics model were obtained for the decolorization process. Hydrodynamics of the packed bed reactor were investigated via a thorough computational fluid dynamics (CFD) simulation using Eulerian approach in axisymmetric space and results were validated using experimental RTD curves and decolorization efficiencies. Ultimately, process simulation was utilized to obtain design parameters of the packed bed reactor in recirculating mode with 99.1% decolorization efficiency. The knowledge obtained through this study can be used to design and scale-up continuous and efficient bioreactors for treatment of wastewater. © 2018 Institution of Chemical Engineers