A Efficient, Metal-Free and Sustainable Synthesis, C-S Linked by Simple C-H Thiocyanation of 4-Aminocoumarin or 4-(N-Aryl)Aminocoumarin Derivativess

A Efficient, Metal-Free and Sustainable Synthesis, C-S Linked by Simple C-H Thiocyanation of 4-Aminocoumarin or 4-(N-Aryl)Aminocoumarin Derivativess Publisher

Askarzadeh M¹ ; Moazzam A² ; Vojdanitalab K² ; Hosseini S³ ; Adib M¹ ; Mahdavi M²

Show Affiliations

1. School of Chemistry, College of Science, University of Tehran, Iran
2. Endocrinology and Metabolism Research Center, Endocrinology and Metabolism Clinical Sciences Institute, Tehran University of Medical Sciences, Tehran, Iran
3. Shahid Beheshti University of Medical Sciences, Tehran, Iran

Source: Tetrahedron Published:2023

Abstract

In the present study, we describe the successful development of a novel and efficient C(sp2)−H thiocyanation reaction of 4-aminocoumarin and 4-(N-aryl)aminocoumarin derivatives with readily available using KSCN as thiocyanating agent and K2S2O8 as an oxidant in ACN under the air atmosphere and room temperature. The most notable point, the reaction proceeded smoothly without the addition of any metal catalyst or strong oxidant and heat, ultimately minimizing the production of chemical waste. The advantages of this reaction met the requirements of green and sustainable synthetic chemistry and may be widely used in organic synthesis and pharmaceutical chemistry. © 2022 Elsevier Ltd

Style	Citing Format
MLA	Askarzadeh M, et al.. "A Efficient, Metal-Free and Sustainable Synthesis, C-S Linked by Simple C-H Thiocyanation of 4-Aminocoumarin or 4-(N-Aryl)Aminocoumarin Derivativess." Tetrahedron, vol. 134, no. , 2023, pp. -.
APA	Askarzadeh M, Moazzam A, Vojdanitalab K, Hosseini S, Adib M, Mahdavi M (2023). A Efficient, Metal-Free and Sustainable Synthesis, C-S Linked by Simple C-H Thiocyanation of 4-Aminocoumarin or 4-(N-Aryl)Aminocoumarin Derivativess. Tetrahedron, 134(), -.
Chicago	Askarzadeh M, Moazzam A, Vojdanitalab K, Hosseini S, Adib M, Mahdavi M. "A Efficient, Metal-Free and Sustainable Synthesis, C-S Linked by Simple C-H Thiocyanation of 4-Aminocoumarin or 4-(N-Aryl)Aminocoumarin Derivativess." Tetrahedron 134, no. (2023): -.
Harvard	Askarzadeh M et al. (2023) 'A Efficient, Metal-Free and Sustainable Synthesis, C-S Linked by Simple C-H Thiocyanation of 4-Aminocoumarin or 4-(N-Aryl)Aminocoumarin Derivativess', Tetrahedron, 134(), pp. -.
Vancouver	Askarzadeh M, Moazzam A, Vojdanitalab K, Hosseini S, Adib M, Mahdavi M. A Efficient, Metal-Free and Sustainable Synthesis, C-S Linked by Simple C-H Thiocyanation of 4-Aminocoumarin or 4-(N-Aryl)Aminocoumarin Derivativess. Tetrahedron. 2023;134():-.
BibTex	@article{ author = {Askarzadeh M and Moazzam A and Vojdanitalab K and Hosseini S and Adib M and Mahdavi M}, title = {A Efficient, Metal-Free and Sustainable Synthesis, C-S Linked by Simple C-H Thiocyanation of 4-Aminocoumarin or 4-(N-Aryl)Aminocoumarin Derivativess}, journal = {Tetrahedron}, volume = {134}, number = {}, pages = {-}, year = {2023} }
RIS	TY - JOUR AU - Askarzadeh M AU - Moazzam A AU - Vojdanitalab K AU - Hosseini S AU - Adib M AU - Mahdavi M TI - A Efficient, Metal-Free and Sustainable Synthesis, C-S Linked by Simple C-H Thiocyanation of 4-Aminocoumarin or 4-(N-Aryl)Aminocoumarin Derivativess JO - Tetrahedron VL - 134 IS - SP - EP - PY - 2023 ER -

Science Communicator Platform

Authors

Authors Affiliations

Abstract