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Deep Eutectic Solvents: Cutting-Edge Applications in Cross-Coupling Reactions Publisher



Hooshmand SE1 ; Afshari R2 ; Ramon DJ3 ; Varma RS4
Authors
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Authors Affiliations
  1. 1. Department of Medical Nanotechnology, Faculty of Advanced Technologies in Medicine, Iran University of Medical Sciences, Tehran, Iran
  2. 2. Department of Physics, Sharif University of Technology, Tehran, Iran
  3. 3. Department of Organic Chemistry, Institute of Organic Synthesis (ISO), Faculty of Sciences, University of Alicante, PO Box 99, Alicante, 03080, Spain
  4. 4. Regional Centre of Advanced Technologies and Materials, Palacky University, Olomouc Slechtitelu 27, Olomouc, 783 71, Czech Republic

Source: Green Chemistry Published:2020


Abstract

Deep eutectic solvents (DESs), surmised as the organic reaction medium of the century, have reverberated a new symphony throughout the present green millennium. A brief historical account of the DES systems and their physicochemical properties as task-specific and designer solvents for cross-coupling reactions are appraised including the hole theory that explains the underlying mechanistic pathway for this emerging neoteric medium. The insights into cross-coupling reactions and their applications are included, highlighting the significant achievements pertaining to the dual role of DESs as a solvent and catalyst. In addition, popular name-reactionsfor the carbon-carbon and carbon-heteroatom bond formations related to the nature of DESs and the core optimum conditions are included. The review also encompasses the novel approaches to privileged catalytic systems and identify the voids left in cross-coupling reactions where DES systems have not made inroads yet. Finally, the challenges of utilizing the neoteric derivatives of DES for these reactions are expounded. © 2020 The Royal Society of Chemistry.
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