Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties

Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties Publisher

Seidi F¹ ; Jouyandeh M^{2, 3} ; Paran SMR² ; Esmaeili A⁴ ; Karami Z² ; Livi S⁵ ; Habibzadeh S⁶ ; Vahabi H³ ; Ganjali MR^{2, 7} ; Saeb MR³

Show Affiliations

1. Provincial Key Lab of Pulp and Paper Science and Technology and Joint International Research Lab of Lignocellulosic Functional Materials, Nanjing Forestry University, Nanjing, 210037, China
2. Center of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, Iran
3. Universite de Lorraine, CentraleSupelec, LMOPS, Metz, F-57000, France
4. Department of Chemical Engineering, School of Engineering Technology and Industrial Trades, College of the North Atlanticâ€”Qatar, Arab League St, Doha, 24449, Qatar
5. Univ Lyon, INSA Lyon, CNRS, IMP UMR 5223, Villeurbanne, F-69621, France
6. Department of Chemical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran, Iran
7. Biosensor Research Center, Endocrinology and Metabolism Molecular-Cellular Sciences Institute, Tehran University of Medical Sciences, Tehran, Iran

Source: Colloids and Surfaces A: Physicochemical and Engineering Aspects Published:2021

Abstract

Ionic liquid-based N-octadecyl-N'-octadecyl imidazolium iodide functionalized layered double hydroxide (LDH-IM) was synthesized for manufacturing high-performance epoxy nanocomposites. Nonisothermal differential scanning calorimetry (DSC) was performed to study cure kinetics of epoxy reinforced قث with LDH and LDH-IM. Incorporation of Mg-Al-CO3 LDH into epoxy hindered the curing reaction, as detected by dimensionless Cure Index (CI). By contrast, epoxy/LDH-IM cured Good and Excellent due to imidazolium ionic liquid. Higher activation energy for completely cured epoxy/LDH-IM nanocomposite was obtained compared to epoxy and epoxy/LDH nanocomposites. The curing reaction rate was obtained by calculation of the orders of instantaneous autocatalytic and non-catalytic reactions, and optimal kinetic parameters based on isoconversional methods were in good agreement with experimental cure reaction rates. Lower value of Tg for epoxy/LDH nanocomposite compared to the neat epoxy signified weak interactions between Mg-Al-CO3-LDH and epoxy matrix, while a higher Tg was obtained for epoxy/LDH-IM. Network degradation kinetics of the samples was also investigated. The higher decomposition activation energy for epoxy/LDH-IM approved strong interfacial adhesion in the assigned system. The highly reactive nature of the developed LDH-IM gives reason for its usage for developing highly curable epoxy with high thermal and mechanical properties. © 2020 Elsevier B.V.

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Style	Citing Format
MLA	Seidi F, et al.. "Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties." Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 611, no. , 2021, pp. -.
APA	Seidi F, Jouyandeh M, Paran SMR, Esmaeili A, Karami Z, Livi S, Habibzadeh S, Vahabi H, Ganjali MR, Saeb MR (2021). Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 611(), -.
Chicago	Seidi F, Jouyandeh M, Paran SMR, Esmaeili A, Karami Z, Livi S, Habibzadeh S, Vahabi H, Ganjali MR, Saeb MR. "Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties." Colloids and Surfaces A: Physicochemical and Engineering Aspects 611, no. (2021): -.
Harvard	Seidi F et al. (2021) 'Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties', Colloids and Surfaces A: Physicochemical and Engineering Aspects, 611(), pp. -.
Vancouver	Seidi F, Jouyandeh M, Paran SMR, Esmaeili A, Karami Z, Livi S, et al.. Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2021;611():-.
BibTex	@article{ author = {Seidi F and Jouyandeh M and Paran SMR and Esmaeili A and Karami Z and Livi S and Habibzadeh S and Vahabi H and Ganjali MR and Saeb MR}, title = {Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties}, journal = {Colloids and Surfaces A: Physicochemical and Engineering Aspects}, volume = {611}, number = {}, pages = {-}, year = {2021} }
RIS	TY - JOUR AU - Seidi F AU - Jouyandeh M AU - Paran SMR AU - Esmaeili A AU - Karami Z AU - Livi S AU - Habibzadeh S AU - Vahabi H AU - Ganjali MR AU - Saeb MR TI - Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects VL - 611 IS - SP - EP - PY - 2021 ER -

Style

Citing Format

MLA

Seidi F, et al.. "Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties." Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 611, no. , 2021, pp. -.

APA

Seidi F, Jouyandeh M, Paran SMR, Esmaeili A, Karami Z, Livi S, Habibzadeh S, Vahabi H, Ganjali MR, Saeb MR (2021). Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 611(), -.

Chicago

Seidi F, Jouyandeh M, Paran SMR, Esmaeili A, Karami Z, Livi S, Habibzadeh S, Vahabi H, Ganjali MR, Saeb MR. "Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties." Colloids and Surfaces A: Physicochemical and Engineering Aspects 611, no. (2021): -.

Harvard

Seidi F et al. (2021) 'Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties', Colloids and Surfaces A: Physicochemical and Engineering Aspects, 611(), pp. -.

Vancouver

Seidi F, Jouyandeh M, Paran SMR, Esmaeili A, Karami Z, Livi S, et al.. Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2021;611():-.

BibTex

@article{ author = {Seidi F and Jouyandeh M and Paran SMR and Esmaeili A and Karami Z and Livi S and Habibzadeh S and Vahabi H and Ganjali MR and Saeb MR}, title = {Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties}, journal = {Colloids and Surfaces A: Physicochemical and Engineering Aspects}, volume = {611}, number = {}, pages = {-}, year = {2021} }

RIS

TY - JOUR
AU - Seidi F
AU - Jouyandeh M
AU - Paran SMR
AU - Esmaeili A
AU - Karami Z
AU - Livi S
AU - Habibzadeh S
AU - Vahabi H
AU - Ganjali MR
AU - Saeb MR
TI - Imidazole-Functionalized Nitrogen-Rich Mg-Al-Co3 Layered Double Hydroxide for Developing Highly Crosslinkable Epoxy With High Thermal and Mechanical Properties
JO - Colloids and Surfaces A: Physicochemical and Engineering Aspects
VL - 611
IS -
SP -
EP -
PY - 2021
ER -

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