Pd@Py2pz@Msn As a Novel and Efficient Catalyst for C

Pd@Py2pz@Msn As a Novel and Efficient Catalyst for C–C Bond Formation Reactions Publisher

Sayahi MH¹ ; Toosibashi M² ; Bahmaei M¹ ; Lijan H² ; Mamani L³ ; Mahdavi M⁴ ; Bahadorikhalili S⁵

Show Affiliations

1. Department of Chemistry, Payame Noor University (PNU), Tehran, Iran
2. School of Chemistry, College of Science, University of Tehran, Tehran, Iran
3. Department of Nanotechnology, Agricultural Biotechnology Research Institute of Iran (ABRII), Agricultural Research Education and Extension Organization (AREEO), Karaj, Iran
4. Endocrinology and Metabolism Research Center, Endocrinology and Metabolism Clinical Sciences Institute, Tehran University of Medical Sciences, Tehran, Iran
5. Department of Electronic Engineering, Universitat Rovira i Virgili, Tarragona, Spain

Source: Frontiers in Chemistry Published:2022

Abstract

In this study, a novel catalyst is introduced based on the immobilization of palladium onto dipyrido (3,2-a:2′,3′-c) phenazine–modified mesoporous silica nanoparticles. The dipyrido (3,2-a:2′,3′-c) phenazine (Py2PZ) ligand is synthesized in a simple method from the reaction of 1,10-phenanthroline-5,6-dione and 3,4-diaminobenzoic acid as starting materials. The ligand is used to functionalize mesoporous silica nanoparticles (MSNs) and modify their surface chemistry for the immobilization of palladium. The palladium-immobilized dipyrido (3,2-a:2′,3′-c) phenazine–modified mesoporous silica nanoparticles (Pd@Py2PZ@MSNs) are synthesized and characterized by several characterization techniques, including TEM, SEM, FT-IR, TGA, ICP, XRD, and EDS analyses. After the careful characterization of Pd@Py2PZ@MSNs, the activity and efficiency of this catalyst is examined in carbon–carbon bond formation reactions. The results are advantageous in water and the products are obtained in high isolated yields. In addition, the catalyst showed very good reusability and did not show significant loss in activity after 10 sequential runs. Copyright © 2022 Sayahi, Toosibashi, Bahmaei, Lijan, Ma'Mani, Mahdavi and Bahadorikhalili.

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Mohammad Mahdavi (6)

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Style	Citing Format
MLA	Sayahi MH, et al.. "Pd@Py2pz@Msn As a Novel and Efficient Catalyst for C–C Bond Formation Reactions." Frontiers in Chemistry, vol. 10, no. , 2022, pp. -.
APA	Sayahi MH, Toosibashi M, Bahmaei M, Lijan H, Mamani L, Mahdavi M, Bahadorikhalili S (2022). Pd@Py2pz@Msn As a Novel and Efficient Catalyst for C–C Bond Formation Reactions. Frontiers in Chemistry, 10(), -.
Chicago	Sayahi MH, Toosibashi M, Bahmaei M, Lijan H, Mamani L, Mahdavi M, Bahadorikhalili S. "Pd@Py2pz@Msn As a Novel and Efficient Catalyst for C–C Bond Formation Reactions." Frontiers in Chemistry 10, no. (2022): -.
Harvard	Sayahi MH et al. (2022) 'Pd@Py2pz@Msn As a Novel and Efficient Catalyst for C–C Bond Formation Reactions', Frontiers in Chemistry, 10(), pp. -.
Vancouver	Sayahi MH, Toosibashi M, Bahmaei M, Lijan H, Mamani L, Mahdavi M, et al.. Pd@Py2pz@Msn As a Novel and Efficient Catalyst for C–C Bond Formation Reactions. Frontiers in Chemistry. 2022;10():-.
BibTex	@article{ author = {Sayahi MH and Toosibashi M and Bahmaei M and Lijan H and Mamani L and Mahdavi M and Bahadorikhalili S}, title = {Pd@Py2pz@Msn As a Novel and Efficient Catalyst for C–C Bond Formation Reactions}, journal = {Frontiers in Chemistry}, volume = {10}, number = {}, pages = {-}, year = {2022} }
RIS	TY - JOUR AU - Sayahi MH AU - Toosibashi M AU - Bahmaei M AU - Lijan H AU - Mamani L AU - Mahdavi M AU - Bahadorikhalili S TI - Pd@Py2pz@Msn As a Novel and Efficient Catalyst for C–C Bond Formation Reactions JO - Frontiers in Chemistry VL - 10 IS - SP - EP - PY - 2022 ER -

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