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Synthesis and Characterization of Sm2(Moo4)3, Sm2(Moo4)3/Go and Sm2(Moo4)3/C3n4 Nanostructures for Improved Photocatalytic Performance and Their Anti-Cancer the Mcf-7 Cells Publisher



Behvandi S1 ; Sobhaninasab A2, 3 ; Karimi MA1 ; Sohouli E4 ; Karimi M5 ; Ganjali MR5, 6 ; Ahmadi F7, 8 ; Rahiminasrabadi M9, 10
Authors
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Authors Affiliations
  1. 1. Department of Chemistry, Payame Noor University, Tehran, Iran
  2. 2. Social Determinants of Health (SDH) Research Center, Kashan University of Medical Sciences, Kashan, Iran
  3. 3. Core Research Lab, Kashan University of Medical Sciences, Kashan, Iran
  4. 4. Young Researchers and Elite Club, Science and Research Branch, Islamic Azad University, Tehran, Iran
  5. 5. Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran
  6. 6. Biosensor Research Center, Endocrinology & Metabolism Molecular‑Cellular Sciences Institute, Tehran University of Medical Sciences, Tehran, Iran
  7. 7. Physiology Research Center, Iran University of Medical Sciences, Tehran, 1449614535, Iran
  8. 8. Department of Medicinal Chemistry, School of Pharmacy-International Campus, Iran University of Medical Sciences, Tehran, Iran
  9. 9. Chemical Injuries Research Center, Systems Biology and Poisonings Institute, Baqiyatallah University of Medical Sciences, Tehran, Iran
  10. 10. Faculty of Pharmacy, Baqiyatallah University of Medical Sciences, Tehran, Iran

Source: Polyhedron Published:2020


Abstract

Samarium molybdate nanoparticles (Sm2(MoO4)3) were prepared through a hydrothermal procedure and were used to form various composites with graphene oxide (GO) and carbon nitride (C3N4). The changes in the dimensions and morphology of the products were prepared using template agents like cetyltrimethyl ammonium bromide (CTAB), Sodium dodecyl sulfate (SDS) (≥90%), Triton X-100 (90%), Polyvinyl alcohol (95%), Ethylene glycol (≥99%), and polyvinylpyrrolidone (PVP). DRS analysis indicated band gap for the Sm2(MoO4), Sm2(MoO4)3/GO, and Sm2(MoO4)3/C3N4 as 3.75, 3.15, and 3.4 respectively. The characteristics of the prepared nanostructures were studied through X-ray diffraction (XRD), energy dispersive X-ray (EDX), and scanning electron microscopy (SEM). Finally, the activity of the prepared Sm2(MoO4)3 as photo-catalysts for the degradation of different organic dyes such as methyl orange (MO), methylene blue (MB), and rhodamine B (Rh B) was evaluated. The photocatalytic property of Sm2(MoO4)3/C3N4 and Sm2(MoO4)3/GO for the degradation of MO, was obtained. Based on the empirical data Sm2(MoO4)3/C3N4 had the strongest photodegradation effect as compared to the other compounds tested after around 40 min. BET analysis revealed that the specific surface area of the Sm2(MoO4)3 nanocomposite prepared using C3N4 is 15 times that of in the absence of C3N4. Also, the cytotoxicity of synthesized samples was evaluated using MTT assay against human cell lines MCF-7 (cancer), and its IC50 was about 125 mg/L. © 2020
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