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Au-Modified Organic/Inorganic Mwcnt/Cu/Pani Hybrid Nanocomposite Electrode for Electrochemical Determination of Nitrate Ions Publisher Pubmed



Motaghedifard MH1 ; Pourmortazavi SM2 ; Alibolandi M1, 3 ; Mirsadeghi S4
Authors
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Authors Affiliations
  1. 1. Research and Development Center, Pakian Kavir Industrial Group, Kashan, Iran
  2. 2. Faculty of Chemistry and Chemical Engineering, Malek Ashtar University of Technology, Tehran, Iran
  3. 3. Department of Analytical Chemistry, Faculty of Chemistry, University of Kashan, Kashan, Iran
  4. 4. Endocrinology and Metabolism Research Center, Endocrinology and Metabolism Clinical Sciences Institute, Tehran University of Medical Sciences, Tehran, 1411713137, Iran

Source: Microchimica Acta Published:2021


Abstract

A new electrochemical sensor is reported for the based on the application of noble bimetal nanoparticles (gold and copper) to polymeric-carbon-modifiers for the reduction of nitrate. This sensor was designed for nitrate ion measurement at the surface of pencil graphite electrode modified by a nanocomposite. The modification was the electrosynthesis of gold nanoparticles on the MWCNT/copper-polyaniline (Cu-PANI) nanocomposite. Physicochemical properties of the synthesized hybrid nanocomposites and their surface performance efficiency are characterized using microscopic, spectroscopic, and electrochemical techniques. At optimized pH, the nitrate peak current (at working potential of 1084 mV versus Ag/AgCl reference electrode) was linear in the concentration range 0.8–30.0 μM with a detection limit of 0.09 μM using differential pulse voltammetry. Modified sensor was successfully implemented to quantify nitrate ions in wastewater resulting from the production line for industrial barium chromate and an example of aqueduct water with appropriate recovery levels. Graphical abstract: [Figure not available: see fulltext.]. © 2021, The Author(s), under exclusive licence to Springer-Verlag GmbH, AT part of Springer Nature.
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