Rhodium-Catalyzed Transformations of Diazo Compounds Via a Carbene-Based Strategy: Recent Advances

Rhodium-Catalyzed Transformations of Diazo Compounds Via a Carbene-Based Strategy: Recent Advances Publisher

Doraghi F¹ ; Baghershahi P² ; Ghasemi M³ ; Mahdavi M¹ ; Alharrasi A³

Show Affiliations

1. Endocrinology and Metabolism Research Center, Endocrinology and Metabolism Clinical Sciences Institute, Tehran University of Medical Sciences, Tehran, Iran
2. Pharmaceutical and Heterocyclic Chemistry Research Laboratory, Department of Chemistry, Iran University of Science and Technology, Tehran, Iran
3. Natural and Medical Sciences Research Center (NMSRC), University of Nizwa, Nizwa, 616, Oman

Source: RSC Advances Published:2024

Abstract

Diazo compounds are known to be good coupling partners in the synthesis of heterocycles, carbocycles and functionalized molecules via a rhodium carbene-based strategy. Many heterocyclic and carbocyclic compounds, including isoquinolones and isocoumarins, quinoxalines, indoles, pyrrones, benzothazines, enaminones, benzenes and seven-membered rings, can be constructed using this rhodium-catalyzed system. The reaction mechanism involves C-H activation, carbene insertion and an annulation/functionalization sequence. This review describes the progress made in the last five years in rhodium-catalyzed transformations of diazo compounds as easily accessible precursors in organic chemistry. © 2024 The Royal Society of Chemistry.

Style	Citing Format
MLA	Doraghi F, et al.. "Rhodium-Catalyzed Transformations of Diazo Compounds Via a Carbene-Based Strategy: Recent Advances." RSC Advances, vol. 14, no. 53, 2024, pp. 39337-39352.
APA	Doraghi F, Baghershahi P, Ghasemi M, Mahdavi M, Alharrasi A (2024). Rhodium-Catalyzed Transformations of Diazo Compounds Via a Carbene-Based Strategy: Recent Advances. RSC Advances, 14(53), 39337-39352.
Chicago	Doraghi F, Baghershahi P, Ghasemi M, Mahdavi M, Alharrasi A. "Rhodium-Catalyzed Transformations of Diazo Compounds Via a Carbene-Based Strategy: Recent Advances." RSC Advances 14, no. 53 (2024): 39337-39352.
Harvard	Doraghi F et al. (2024) 'Rhodium-Catalyzed Transformations of Diazo Compounds Via a Carbene-Based Strategy: Recent Advances', RSC Advances, 14(53), pp. 39337-39352.
Vancouver	Doraghi F, Baghershahi P, Ghasemi M, Mahdavi M, Alharrasi A. Rhodium-Catalyzed Transformations of Diazo Compounds Via a Carbene-Based Strategy: Recent Advances. RSC Advances. 2024;14(53):39337-39352.
BibTex	@article{ author = {Doraghi F and Baghershahi P and Ghasemi M and Mahdavi M and Alharrasi A}, title = {Rhodium-Catalyzed Transformations of Diazo Compounds Via a Carbene-Based Strategy: Recent Advances}, journal = {RSC Advances}, volume = {14}, number = {53}, pages = {39337-39352}, year = {2024} }
RIS	TY - JOUR AU - Doraghi F AU - Baghershahi P AU - Ghasemi M AU - Mahdavi M AU - Alharrasi A TI - Rhodium-Catalyzed Transformations of Diazo Compounds Via a Carbene-Based Strategy: Recent Advances JO - RSC Advances VL - 14 IS - 53 SP - 39337 EP - 39352 PY - 2024 ER -

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