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Further Comments on “Experimental Measurements, Equilibrium Study and Model Correlation of Methyl Paraben in Ethanol and Methanol Aqueous Solutions From = (293.15 to 323.15) K” Publisher



Jouyban A1, 2 ; Martinez F3
Authors
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Authors Affiliations
  1. 1. Pharmaceutical Analysis Research Center and Faculty of Pharmacy, Tabriz University of Medical Sciences, Tabriz, Iran
  2. 2. Digestive Diseases Research Institute, Tehran University of Medical Sciences, Tehran, Iran
  3. 3. Grupo de Investigaciones Farmaceutico-Fisicoquimicas, Departamento de Farmacia, Facultad de Ciencias, Universidad Nacional de Colombia – Sede Bogota, Cra. 30 No. 45-03, Bogota, D.C., Colombia
  4. 4. Department of Chemistry, University of North Texas, Denton, 76203-5070, TX, United States

Source: Journal of Molecular Liquids Published:2020


Abstract

The experimental solubility data of methyl paraben in ethanol + water and methanol + water binary solvent mixtures at temperature range from (293.15 to 323.15) K have carefully been reanalyzed and some recommendations were proposed. In addition, preferential solvation analyses based on the inverse Kirkwood-Buff integrals show that this compound is preferentially solvated by water in water-rich mixtures in both binary systems but preferentially solvated by the cosolvent in the composition region of 0.24 < x1 < 1.00 for ethanol + water mixtures and the composition region of 0.31 < x1 < 1.0 for methanol + water mixtures. © 2020 Elsevier B.V.
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