Rhodium(Ii)-Catalyzed Denitrogenative Transformations of N-Sulfonyl-1,2,3-Triazoles

Rhodium(Ii)-Catalyzed Denitrogenative Transformations of N-Sulfonyl-1,2,3-Triazoles Publisher

Doraghi F¹ ; Hossein Morshedsolouk M² ; Ghofrani S² ; Larijani B¹ ; Mahdavi M¹

Show Affiliations

1. Endocrinology and Metabolism Research Center, Endocrinology and Metabolism Clinical Sciences Institute, Tehran University of Medical Sciences, Tehran, Iran
2. School of Chemistry, College of Science, University of Tehran, Tehran, Iran

Source: European Journal of Organic Chemistry Published:2025

Abstract

N-Sulfonyl-1,2,3-triazoles are valuable precursors for the generation of α-imino carbene intermediates in the presence of the metal catalysts, especially rhodium(II) complexes. Due to the presence of electrophilic carbene and nucleophilic nitrogen, these reactive intermediates can easily be incorporated into many annulations, cycloadditions, C−H or O/N/S−H bond insertions and functionalization reactions. A large number of pharmaceutically important nitrogen-based building blocks can be constructed via this direct and atom-economical carbene strategy. In this review, we have described the transformations of N-sulfonyl-1,2,3-triazoles based on α-imino rhodium(II) carbene intermediates. © 2024 Wiley-VCH GmbH.

Style	Citing Format
MLA	Doraghi F, et al.. "Rhodium(Ii)-Catalyzed Denitrogenative Transformations of N-Sulfonyl-1,2,3-Triazoles." European Journal of Organic Chemistry, vol. 28, no. 2, 2025, pp. -.
APA	Doraghi F, Hossein Morshedsolouk M, Ghofrani S, Larijani B, Mahdavi M (2025). Rhodium(Ii)-Catalyzed Denitrogenative Transformations of N-Sulfonyl-1,2,3-Triazoles. European Journal of Organic Chemistry, 28(2), -.
Chicago	Doraghi F, Hossein Morshedsolouk M, Ghofrani S, Larijani B, Mahdavi M. "Rhodium(Ii)-Catalyzed Denitrogenative Transformations of N-Sulfonyl-1,2,3-Triazoles." European Journal of Organic Chemistry 28, no. 2 (2025): -.
Harvard	Doraghi F et al. (2025) 'Rhodium(Ii)-Catalyzed Denitrogenative Transformations of N-Sulfonyl-1,2,3-Triazoles', European Journal of Organic Chemistry, 28(2), pp. -.
Vancouver	Doraghi F, Hossein Morshedsolouk M, Ghofrani S, Larijani B, Mahdavi M. Rhodium(Ii)-Catalyzed Denitrogenative Transformations of N-Sulfonyl-1,2,3-Triazoles. European Journal of Organic Chemistry. 2025;28(2):-.
BibTex	@article{ author = {Doraghi F and Hossein Morshedsolouk M and Ghofrani S and Larijani B and Mahdavi M}, title = {Rhodium(Ii)-Catalyzed Denitrogenative Transformations of N-Sulfonyl-1,2,3-Triazoles}, journal = {European Journal of Organic Chemistry}, volume = {28}, number = {2}, pages = {-}, year = {2025} }
RIS	TY - JOUR AU - Doraghi F AU - Hossein Morshedsolouk M AU - Ghofrani S AU - Larijani B AU - Mahdavi M TI - Rhodium(Ii)-Catalyzed Denitrogenative Transformations of N-Sulfonyl-1,2,3-Triazoles JO - European Journal of Organic Chemistry VL - 28 IS - 2 SP - EP - PY - 2025 ER -

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